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Synovial joints, critical for limb biomechanics, rely on sophisticated lubrication systems to minimize wear. Disruptions, whether from injury or disease, often necessitate joint replacements. While additive manufacturing offers personalized implants, ensuring wear resistance remains a challenge. This study delves into the potential of Ti3C2Tx and Mo2TiC2Tx nanosheets in mitigating wear of additively manufactured cobalt-chromium tungsten alloy substrates when incorporated as additives into synovial fluid. The colloidal solutions demonstrate an excellent stability, a crucial factor for reproducible assays and potential clinical applicability. Analysis of contact angles and surface tensions reveals MXene-induced alterations in substrate wettability, while maintaining their general hydrophilic character. Viscosity analysis indicates that MXene addition reduces the dynamic viscosity, particularly at higher concentrations above 5 mg/mL, thus enhancing dispersion and lubrication properties. Friction and wear tests demonstrate a dependency on the MXene concentration, while Ti3C2Tx exhibits stable friction coefficients and up to 77 % wear reduction at 5 mg/mL, which was attributed to the formation of a wear-protecting tribo-film (amorphous carbon and MXene nano-sheets). Our findings suggest that Ti3C2Tx, when supplied in favorable concentrations, holds promise for reducing wear in biotribological applications, offering avenues for future research into optimizing MXene utilization in load-bearing joint replacements and other biomedical devices. 

Abstract Recent advances in 2D nanomaterials, such as graphene, transition metal dichalcogenides, boron nitride, MXenes, allow not only to discover several new nanoscale phenomena but also to address the scientific and industrial challenges associated with the design of systems with desired physical properties. One of the great challenges for mechanical systems is associated with addressing friction and wear problems in machine elements. In this review, the beneficial properties of layered 2D materials that enable the control of their tribological behavior and make them excellent candidates for efficient friction and wear reduction in dry‐running and boundary lubricated machine components are summarized. The recent studies highlighting the successful implementation of 2D structures when used as solid lubricant coatings or reinforcement phases in composites for various machine components including sliding and rolling bearings, gears, and seals are overviewed. The examples presented in the studies demonstrate the great potential for 2D materials to address the energy‐saving needs by friction and wear reduction.